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Stereoselective additions of grignard reagents to masked imines and iminium ions

✍ Scribed by Michel Bortolussi; Christophe Cinquin; Robert Bloch

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
177 KB
Volume
37
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Stereoselective Add
ChemInform Abstract: Stereoselective Additions of Grignard Reagents to Masked Imines and Iminium Ions.
✍ M. BORTOLUSSI; C. CINQUIN; R. BLOCH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Stereoselective intramolecular addition
Stereoselective intramolecular addition of a grignard reagent to the terminal trimethylsilylethene moiety
✍ Kiitiro Utimoto; Katsuharu Imi; Hiroshi Shiragami; Sadao Fujikura; Hitosi Nozaki πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 115 KB

Reaction of (E)-6-bromo-3-methyl-1-trimethylsilyl-1-hexene with magnesium produces corresponding Grignard reagent which intramolecularly adds to the silylethene moiety from the less hindered side affording a single stereoisomer.