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Stereoselective Addition of Dimethyl Diselenide to Trimethylethynylsilane

โœ Scribed by V. A. Potapov; S. V. Amosova; O. V. Belozerova; O. G. Yarosh; D. V. Gendin; M. G. Voronkov

Book ID
111608298
Publisher
Springer
Year
2003
Tongue
English
Weight
26 KB
Volume
73
Category
Article
ISSN
1070-3632

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Diphenyl diselenide-promoted radical add
Diphenyl diselenide-promoted radical addition of benzeneselenol to acetylenes
โœ Akiya Ogawa; Ryoichi Obayashi; Masahito Sekiguchi; Teruyuki Masawaki; Nobuaki Ka ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

Diphenyl diselenide promotes the rudicul addition of benzeneselenol to inactivated acetylenes upon irradiation through Pyrex with a tungsten lump. The addition may proceed by a radical chain mechanism that involves ph~n\_y!ylsaleo radical (PhSe-) as the key species, generated by the photolysis of(Ph