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Free-radical additions of diselenides to dimethyl acetylenedicarboxylate, methyl propiolate, and dimethyl maleate

✍ Scribed by Back, Thomas G.; Krishna, M. Vijaya

Book ID
120412932
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
552 KB
Volume
53
Category
Article
ISSN
0022-3263

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Aminal-catalyzed isomerization of and ad
Aminal-catalyzed isomerization of and addition to dimethyl maleate
✍ A.Gilbert Cook; Andrea B Voges; Aster E Kammrath πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 178 KB

The amine moiety of aminals adds to dimethyl maleate via azomethine ylid intermediates. The products of this reaction, in turn, cause dimethyl maleate to isomerize to dimethyl fumarate.