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Stereoselective Access to New Half-Sandwich Complexes Containing an Isodicyclopentadienyl Ligand

✍ Scribed by Gentil, Sébastien; Pirio, Nadine; Meunier, Philippe; Gallucci, Judith C.; Schloss, Jeffrey D.; Paquette, Leo A.

Book ID
126083594
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
53 KB
Volume
19
Category
Article
ISSN
0276-7333

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## Abstract The d^6^ low‐spin Mn^I^ half‐sandwich dinuclear complexes of the type [{Mn(MeC~5~H~4~)(R~2~PCH~2~CH~2~PR~2~)=C=C(SnMe~3~)}~2~{X}] (X = {μ‐1,4‐C~6~H~4~}, R = Me, 2a; X = {μ‐1,4‐C~6~H~4~}, R = Et, 2b; X = {μ‐1,3‐C~6~H~4~}, R = Me, 3a; X = {μ‐1,3‐C~6~H~4~}, R = Et, 3b; X = {μ‐4,4‐C~6~H~4~‐