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Stereoselective [6 + 4] cycloadditions of methylfulvene and phenylfulvene to tropone

✍ Scribed by K.N. Houk; L.J. Luskus; N.S. Bhacca

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 181 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84832-2

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✦ Synopsis

We recently reported the periaelective formation of 2:l adduct && in the reaction of tropone with dimethylfu1vene.l This observation of an unprecedented reaction of a fulvene as a 6~ addend has led us to investigate further the mechanism of this reaction.

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