Stereoelectronic Properties of N-acetyl-α,β-dehydroamino acid N′-methylamides
✍ Scribed by Małgorzata A. Broda; Barbara Rzeszotarska
- Book ID
- 110268182
- Publisher
- Springer Netherlands
- Year
- 1998
- Tongue
- English
- Weight
- 47 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1573-3149
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
The FTIR spectra were analysed in the region of the nu(s)(N-H), AI(C=O) and nu(s)(Calpha=Cbeta) bands for a series of Ac-DeltaXaa-NMe2, where DeltaXaa = DeltaAla, (Z)-DeltaAbu, (Z)-DeltaLeu, (Z)-DeltaPhe and DeltaVal, to determine a predominant solution conformation of these alpha,beta-dehydropeptid
The crystal structure of (Zkacetyl-a,Pdehydrophenylalanine methylamide (monoclinic, Cc, a = 10.241(1), b = 15.252(1), c = 8.643(1) d;, P = 120.98(1Y, 2 = 4) has been solved by x-ray diffraction to an R-factor = 0.048, and compared to that of the h e mologous Gphenylalanine derivative. Molecules are