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Conformational investigation of α, β-dehydropeptides. VIII.*N-Acetyl-α, β-dehydroamino acid N'-methylamides: conformation and electron density perturbation from infrared and theoretical studies

✍ Scribed by BRODA, MALGORZATA A. ;RZESZOTARSKA, BARBARA ;SMELKA, LESZEK ;ROSPENK, MARIA


Book ID
110893613
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
964 KB
Volume
50
Category
Article
ISSN
1397-002X

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Conformational investigation of α,β-dehy
✍ Małgorzata A. Broda; Dawid SiodŁak; Dr Barbara Rzeszotarska 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 337 KB

The FTIR spectra were analysed in the region of the nu(s)(N-H), AI(C=O) and nu(s)(Calpha=Cbeta) bands for a series of Ac-DeltaXaa-NMe2, where DeltaXaa = DeltaAla, (Z)-DeltaAbu, (Z)-DeltaLeu, (Z)-DeltaPhe and DeltaVal, to determine a predominant solution conformation of these alpha,beta-dehydropeptid