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Stereoelectronic effects in the deprotonation of arylalkyl radical cations: meso-ethylanthracenes

โœ Scribed by Tolbert, Laren M.; Khanna, Rajive K.; Popp, Ann E.; Gelbaum, Leslie; Bottomley, Lawrence A.

Book ID
126335769
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
873 KB
Volume
112
Category
Article
ISSN
0002-7863

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Stereoelectronic Inhibition of Deprotona
Stereoelectronic Inhibition of Deprotonation in the Radical Cation of N-Benzylpiperidine: a Contribution to the Debate on the Mechanism of N-Dealkylation of Tertiary Amines
โœ Massimo Bietti; Andrea Cuppoletti; Claudio Dagostin; Cristina Florea; Carlo Gall ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 147 KB ๐Ÿ‘ 2 views

Evidence for a stereoelectronic inhibition of deprotonation of versus electron-transfer routes in the biomimetic oxidative N-dealkylation of tertiary amines: the electron-transfer route the radical cation of N-benzylpiperidine is presented. This stereoelectronic effect, which is due to the cyclic st