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Electronic effects in cyclobutadiene radical cations

โœ Scribed by Courtneidge, John L.; Davies, Alwyn G.; Lusztyk, Janusz

Book ID
121218692
Publisher
The Royal Society of Chemistry
Year
1983
Tongue
English
Weight
190 KB
Volume
16
Category
Article
ISSN
0022-4936

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Towards persistent cyclobutadiene radica
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โœ Q.B. Broxterman; H. Hogeveen; R.F. Kingma ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 217 KB

The persistence of alkyl substituted cyclobutadiene radical cations strongly depends on the method of generation and the size of the alkyl substituents used. Hindered rotation, the consequence of bulky substituents, is observed in the title compounds. Cyclobutadiene radical cations are transient spe