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Stereoelectronic effects in arene exchange of (arene)tricarbonylchromium complexes: internal arene exchange and internal arene catalysis of external arene exchange

✍ Scribed by Traylor, Teddy G.; Goldberg, Martin J.


Book ID
126829664
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
491 KB
Volume
6
Category
Article
ISSN
0276-7333

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Mononuclear Ξ·6-Arene Complexes of Lantha
✍ Mikhail Gorlov; Linda Lejla Hussami; Andreas Fischer; Lars Kloo πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

## Abstract Gallium(III) halides react with cerium(III), ytterbium(III), or dysprosium(III) halides in the presence of alkylated benzenes yielding mononuclear complexes of the general formula [Ln(Ξ·^6^‐arene)(GaX~4~)~3~]. The X‐ray structures of [Ce(C~6~H~5~Me)(GaCl~4~)~3~] (1), [Ce(__p__‐C~6~H~4~Me