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Mechanisms of arene exchange in (arene)tricarbonylchromium compounds: intermolecular and intramolecular exchanges in complexes of propenylbenzene, stilbenes, and 1,1-diphenylethylene

✍ Scribed by Traylor, T. G.; Stewart, Kevin J.


Book ID
120628991
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
926 KB
Volume
108
Category
Article
ISSN
0002-7863

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Arene Complexes of Ξ²-Diketiminato Suppor
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## Abstract A family of isolable solvent separated organoscandium methyl cations stabilized by β‐diketiminato ligands (Ar)NC(CH~3~)CHC(CH~3~)N(Ar) (Ar=2,6‐__i__Pr‐C~6~H~3~, L^Me^) has been prepared by reaction of L^Me^ScR~2~ with [CPh~3~][B(C~6~F~5~)~4~] in the presence of an arene solvent. Arenes