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Stereoelectronic control of intramolecular Michael addition reactions

✍ Scribed by Ellis, Graham W. L.; Johnson, C. David; Rogers, David N.

Book ID
127120810
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
763 KB
Volume
105
Category
Article
ISSN
0002-7863

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In the nucleophilic addition on conjugated olefinic ketones (enones), stereoelectronic effects predict that the intermediate enolate should first be generated in a conformation where the newly formed bond is parallel with the II system of the enolatel. Stereoelectronic parameters predict also that t