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Electronic Effects in Intramolecular Michael Addition Reactions

โœ Scribed by Graham W. L. Ellis; C. David Johnson; David N. Rogers


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
53 KB
Volume
91
Category
Article
ISSN
0037-9646

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Polar effects in radical addition reacti
โœ Giese, Bernd ;He, Jianing ;Mehl, Wolf ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 288 KB ๐Ÿ‘ 2 views

Methyl radicals substituted by one ester or nitrile group are on the borderline between nucleophilic and electrophilic behavior. In addition reactions of these borderline radicals to styrenes, polar effects of both, electron-withdrawing and electron-donating substituents at the alkeae, increase the