Abstraet--Propylene sulphide is polymerized by zinc and cadmium thiolates, the latter being particularly active initiators. The polymerizations are non-terminating and there is a period of accelerating rate after which the rates are first order in monomer and initiator. The monomer is considered to
β¦ LIBER β¦
Stereoelective polymerization of propylene sulphide
β Scribed by N. Spassky; P. Sigwalt
- Book ID
- 107753188
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 512 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0014-3057
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The mechanism of stereoregulation in polymerization reaction is discussed in terms of the two model cases: (i) the growing chain control mechanism, and (ii) catalyst control mechanism. These two mechanisms were observed to be operated in the stereoselective polymerizations of methyloxirane and of te