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The stereoselective and stereoelective polymerizations of some oxiranes

✍ Scribed by Tsuruta, Teiji

Publisher
Wiley (John Wiley & Sons)
Year
1981
Weight
229 KB
Volume
5
Category
Article
ISSN
0025-116X

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✦ Synopsis

The mechanism of stereoregulation in polymerization reaction is discussed in terms of the two model cases: (i) the growing chain control mechanism, and (ii) catalyst control mechanism. These two mechanisms were observed to be operated in the stereoselective polymerizations of methyloxirane and of tert-butyloxirane.

* -isotactic sequences, and vice versa. No influence at all was observed from the chiral structure of growing chain end in determining stereochemical sequences in the polymer molecule.

Results of copolymerization between Dand L-monomer were found to be a useful experimental tool for elucidation of mechanism of stereoregulation.

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