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Stereodynamics and Asymmetric Hydrosilylation with Chiral Rhodium Complexes Containing a Monodentate N-Heterocyclic Carbene.

โœ Scribed by J. W. Faller; Philip P. Fontaine


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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Asymmetric transfer hydrogenation cataly
โœ Ru Jiang; Xiaoli Sun; Wei He; Hui Chen; Yongqing Kuang ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 104 KB ๐Ÿ‘ 2 views

## Abstract A novel chelated ferroceneโ€based planar chiral Nโ€heterocyclic carbeneโ€Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright ยฉ 2009 John Wiley & Sons, L