ChemInform Abstract: N-Heterocyclic Carbene. Part 92. Enantioselective Hydrosilylation with a Chiral N-Heterocyclic Carbene Complex Rhodium(I).
โ Scribed by Sandra C. Zinner; Mei Zhang-Presse; Wolfgang A. Herrmann; Fritz E. Kuehn
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
## Abstract A novel chelated ferroceneโbased planar chiral Nโheterocyclic carbeneโRh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright ยฉ 2009 John Wiley & Sons, L