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Stereodynamics and absolute configuration of stereolabile atropisomers in 2,2-dimethyl-1-aryl-1-indanols

✍ Scribed by Daniele Casarini; Michele Mancinelli; Andrea Mazzanti; Francesca Boschi


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
576 KB
Volume
23
Category
Article
ISSN
0899-0042

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Determination of absolute configuration
✍ Wolfram Krenn; Petra Verdino; Georg Uray; Kurt Faber; C. Oliver Kappe πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 106 KB πŸ‘ 1 views

The absolute configuration of three 4-aryl-3,4-dihydro-2(1H)-pyrimidones (Biginelli compounds, DHPMs) was established by comparison of the typical circular dichroism (CD) spectra of individual enantiomers with reference samples of known absolute configuration. The enantiomers were obtained by semipr