Stereodivergent Addition of Allylmetal R
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Ramón Badorrey; Carlos Cativiela; María D. Díaz-de-Villegas; Roberto Díez; José
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Article
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2002
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John Wiley and Sons
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English
⚖ 108 KB
The addition of allylmetal reagents to N-benzylimines derived from (R)-2,3-di-O-benzylglyceraldehyde has been achieved with high yields and diastereoselectivities. Homoallylamine 2a of syn configuration is obtained preferentially with allylmagnesium bromide, whereas homoallylamine 2a of anti configu