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Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones

✍ Scribed by Choi, Junwon; Martín-Gago, Pablo; Fu, Gregory C.


Book ID
127311643
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
922 KB
Volume
136
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES


Suitably designed chiral amino alcohols:
✍ I. Reiners; J. Martens 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 301 KB

The amino alcohol rac-1-(1,2,3,4-tetrahydroisoquinoline-1-yl)-cyclopentanol was resolved via its O,O'-dibenzoyl-tartaric acid salt. These enantiomeric amino alcohols were used in the enantioselective reduction of prochiral aryl alkyl ketones. The resulting secondary alcohols were obtained in high en