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Stereocontrolled Total Synthesis of (−)-Aurisides A and B

✍ Scribed by Ian Paterson; Gordon J. Florence; Annekatrin C. Heimann; Angela C. Mackay


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
128 KB
Volume
117
Category
Article
ISSN
0044-8249

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ChemInform Abstract: Stereocontrolled To
✍ I. KADOTA; Y. YAMAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Stereocontrolled Total Synthesis of Hemibrevetoxin B. -A linear approach to the total synthesis of title compound (I) is accomplished with high stereoselectivity in 56 steps and 0.75% overall yield from D-mannose. Key step in this synthesis is the intramolecular reaction of γ-alkoxyallylstannanes wi