Stereocontrolled synthesis of quaternary cyclopropyl esters
β Scribed by Bray, Christopher D.; Minicone, Fabrizio
- Book ID
- 111909166
- Publisher
- Royal Society of Chemistry
- Year
- 2010
- Tongue
- English
- Weight
- 574 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1359-7345
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π SIMILAR VOLUMES
The synthesis of enantiomerically pure cyclopropyl boronic esters 12a-d and 13a-d has been achieved. The high-yielding process involves the condensation of readily available alkenyl boronic acids la-d with (2R,3R)-1,4-dimethoxy-(1R,2S)-4c+d and (lS,2S)-4a+bl(lS,2R)-4c+d, respectively, 1,1,4,4-tetrap
Diastereoselective Synthesis of Cyclopropyl Boronic Esters. -A simple and efficient protocol for the conversion of 1-alkynes to 2-alkylcyclopropanols is described. Thus, 1-alkyne-derived alkynyl boronic esters (I) are converted to chiral tartrates (IV) and then subjected to cyclopropanation providi
1998 organo-boron compounds, isocyclic C derivatives organo-boron compounds, isocyclic C derivatives S 0044 ## 06 -199 Synthesis of Enantiomerically Pure Cyclopropyl Boronic Esters. -Enantiomerically pure cyclopropyl boronic esters (V) and (VI), which are synthetic building blocks, are prepared b