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Stereocontrolled Synthesis of Ara-Type Cyclohexenyl Nucleosides

✍ Scribed by Wang, Jing; Viña, Dolores; Busson, Roger; Herdewijn, Piet

Book ID
127013081
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
157 KB
Volume
68
Category
Article
ISSN
0022-3263

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Synthesis of (±) cis-substituted cyclohe
Synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides via a double Mitsunobu-type reaction
✍ Karine Barral; Philippe Halfon; Gérard Pèpe; Michel Camplo 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 66 KB

This letter describes the synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides. The synthesis of cis isomers was successfully achieved by the use of two consecutive Mitsunobu reactions involving an inversion of configuration and a sugar-base condensation.