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Synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides via a double Mitsunobu-type reaction

✍ Scribed by Karine Barral; Philippe Halfon; Gérard Pèpe; Michel Camplo

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
66 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

This letter describes the synthesis of (±) cis-substituted cyclohexenyl and cyclohexanyl nucleosides. The synthesis of cis isomers was successfully achieved by the use of two consecutive Mitsunobu reactions involving an inversion of configuration and a sugar-base condensation.

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