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Stereocontrolled synthesis of (+)- and (−)-iridomyrmecin from citronellene enantiomers

✍ Scribed by A. V. Stepanov; V. V. Veselovsky

Publisher
Springer
Year
1997
Tongue
English
Weight
465 KB
Volume
46
Category
Article
ISSN
1573-9171

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Stereocontrolled Formation of Three Cont
Stereocontrolled Formation of Three Contiguous Stereogenic Centers by Free Radical Cyclization – Synthesis of (+)-Iridomyrmecin and (–)-Iso-iridomyrmecin – Formal Synthesis of δ-Skythantine
✍ Bernd Schöllhorn; Johann Mulzer 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB

## Abstract A synthesis of (__+__)‐iridomyrmecin (**1**), a naturally occurring insecticide with antibiotic properties, via free radical cyclization is described. In this key step, three contiguous stereogenic centers are generated with a high level of stereocontrol. (© Wiley‐VCH Verlag GmbH & Co.