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Stereocontrolled synthesis of 7-hydroxy- and 7-acetoxy-PGI2: New stable PGI2 analogues

✍ Scribed by Kiyoshi Bannai; Takeshi Toru; Takeo Ba; Toshio Tanaka; Noriaki Okamura; Kenzo Watanabe; Seizi Kurozumi

Book ID: 104241532
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 238 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90337-5

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✦ Synopsis

Stable analogues of PGIz, 7-hydroxy-and 7-acetoxy-PGIz, were synthesized from protected PGIz methyl ester G via sulfoxides 6a, 6& through stereocontrolled sulfoxide-sulfenate rearrangement.

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