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Stereocontrolled Synthesis of 5-Acyl-3,4-dihydro-2 H -pyrroles and Related Heterocycles via Intramolecular 2-Propylidene-1,3-bis(silane)−Acylnitrilium Ion Cyclizations †

✍ Scribed by Kercher, Timothy; Livinghouse, Tom

Book ID
119978980
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
1006 KB
Volume
62
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Stereocontrolled Sy
ChemInform Abstract: Stereocontrolled Synthesis of 5-Acyl-3,4-dihydro-2H-pyrroles and Related Heterocycles via Intramolecular 2-Propylidene-1,3-bis(silane)- Acylnitrilium Ion Cyclizations.
✍ T. KERCHER; T. LIVINGHOUSE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

Stereocontrolled Synthesis of 5-Acyl-3,4-dihydro-2H-pyrroles and Related Heterocycles via Intramolecular 2-Propylidene-1,3-bis(silane)-Acylnitrilium Ion Cyclizations. -The title reaction is found to proceed with good to excellent diastereoselectivity. Reduction of prepared δ1-pyrrolines results in s