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Stereocontrolled Glycosidations Using a Heterogeneous Solid Acid, Sulfated Zirconia, for the Direct Syntheses of α- and β-Manno- and 2-Deoxyglucopyranosides.

✍ Scribed by Kazunobu Toshima; Hideyuki Nagai; Ken-ichi Kasumi; Kanako Kawahara; Shuichi Matsumura

Publisher
John Wiley and Sons
Year
2004
Weight
64 KB
Volume
35
Category
Article
ISSN
0931-7597

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Novel Stereocontrolled Glycosidations of 2-Deoxyglucopyranosyl Fluoride Using a Heterogeneous Solid Acid, Sulfated Zirconia (SO 4 /ZrO 2 ). -Use of the environmentally benign solid acid SO 4 /ZrO 2 in glycosidation reactions of 2-deoxy sugars and alcohols provides a simple, stereoselective, and hig