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ChemInform Abstract: Novel Stereocontrolled Glycosidations of 2-Deoxyglucopyranosyl Fluoride Using a Heterogeneous Solid Acid, Sulfated Zirconia (SO4/ZrO2).

✍ Scribed by Kazunobu Toshima; Ken-ichi Kasumi; Shuichi Matsumura

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199937227

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✦ Synopsis

Novel Stereocontrolled Glycosidations of 2-Deoxyglucopyranosyl Fluoride Using a Heterogeneous Solid Acid, Sulfated Zirconia (SO 4 /ZrO 2 ).

-Use of the environmentally benign solid acid SO 4 /ZrO 2 in glycosidation reactions of 2-deoxy sugars and alcohols provides a simple, stereoselective, and high yielding protocol for the preparation of biologically important products possessing a 2-deoxy sugar as a glycosidic component. -

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