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Stereocontrolled formation of cis and trans ring junctions in hydrindane and decalin systems by palladium-catalyzed regioselective and stereospecific hydrogenolysis of allylic formates

โœ Scribed by Mandai, Tadakatsu; Matsumoto, Takaji; Kawada, Mikio; Tsuji, Jiro

Book ID
127114323
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
277 KB
Volume
57
Category
Article
ISSN
0022-3263

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Stereocontrolled formation of cis and tr
Stereocontrolled formation of cis and trans ring junctions in hydrindane, decalin, and steroid systems by palladium-catalyzed regioselective and stereospecific hydrogenolysis of allylic formates
โœ Tadakatsu Mandai; Takaji Matsumoto; Mikio Kawada; Jiro Tsuji ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 724 KB

Both the cis and rruns nng junctions can he generated solechvely in hydrindane, decalin and stercnd systems by the palladium-catalyzed regioselectwe and stereospeafic decarboxylation-hydrogenolysis of allyhc formates. The trans Junctions were formed from 3p allylic formates of decalin and steroid an