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Stereochimie de l'addition de reactifs nucleophiles sur les aldehydes α-halogenes. I) addition du methylate de sodium sur les aldehydes α-bromes.

✍ Scribed by J.J. Riehl; L. Thil


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
170 KB
Volume
10
Category
Article
ISSN
0040-4039

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Etude de l'addition nucleophile de quelq
✍ Odile Ruel; Eric Guittet; Sylvestre Julia 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 200 KB

The >/ 92 % regioselective nucleophilic trans-addition of 2-methyl-2-propanethiol to primary, secondary ond tertiary 1-alkyn-3-ols, catalyzed by 0,l equiv. of potassium hydroxide powder, affords good yields of anti-Markovnikoff products. Pour confirmer la structure du compose (2, R1=R2=CH3,