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Stereochemistry of the ring-opening polymerization of (S)-.beta.-butyrolactone

โœ Scribed by Zhang, Yan; Gross, Richard A.; Lenz, Robert W.


Book ID
120540427
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
908 KB
Volume
23
Category
Article
ISSN
0024-9297

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Stereochemistry of ring opening polymeri
โœ Sigwalt, Pierre ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Wiley (John Wiley & Sons) โš– 775 KB

Stereospecific polymerizations of racemic mixtures of chiral cyclic monomers have been shown to be stereoselective with non chiral initiators and stereoelective with some chiral initiators. The bulkiness of the ring substituents influences the interaction of monomer with initiator and this leads to