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Efficient ring-opening polymerization of a .gamma.-butyrolactone derivative. First anionic double ring-opening polymerization

✍ Scribed by Tadokoro, Atsuhito; Takata, Toshikazu; Endo, Takeshi


Book ID
121424351
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
232 KB
Volume
26
Category
Article
ISSN
0024-9297

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Anionic polymerizations of 1,1-dimethylsilacyclobutane, 1,1-diethylsilacyclobutane and 1-methyl-1-phenylsilacyclobutane were investigated. Addition of 5 mol % of butyllithium to a solution of 1,1-dimethylsilacyclobutane in THF-hexane (1 : 1) at 048ЊC provided poly(1,1-dimethylsilabutane) in 99% yiel