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Stereochemistry of the reaction of strained olefins with iron carbonyls

โœ Scribed by Grandjean, Jean; Laszlo, Pierre; Stockis, Armel


Book ID
126053781
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
252 KB
Volume
96
Category
Article
ISSN
0002-7863

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AS part of an lnvestlgatlon of the iron carbonyl catalysed lsomerlsatlon of allyllc alcohols1'2'3 , Cowherd and van Rosenberg' showed that, whereas the trlcycllc alcohol (1, D = H) lsomerlsed to the ketone (2, D = H) on heating In the presence of iron pentacarbonyl, its eplmer did not react under sl

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We are reporting that the stereospecificity of cis-2-pentene's metathesis is much greater when the initiator is (C6H5)2C=W(CO)51 than when it is any other previously examined, that this high stereospecificity is similar to that shown by cyclic olefins, 3 and accordingly that no special mechanism is