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Stereochemistry of the Peracid Oxidation of Ketones 1

โœ Scribed by Turner, Richard B.


Book ID
127005469
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
606 KB
Volume
72
Category
Article
ISSN
0002-7863

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cl-Lactones have been implicated as reactive intermediates in several types of reactions: the solvolysis of cy-halocarboxylate anions,2 the decomposition of certain peresters,

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Recent reports describe peracid oxidation studies on cyclopropeues as a potential syuthetic approach to an oxabicyclobutaue derivative.2 Eowever, this hetexocyclic system has not yet been obtained, apparently a result of its facile rearraug-t to the i8americ coojugated carbonyl compound as iudicated

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