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Peracid oxidation of cyclopropenones

✍ Scribed by J.K. Crandall; W.W. Conover

Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 165 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)96502-5

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✦ Synopsis

Recent reports describe peracid oxidation studies on cyclopropeues as a potential syuthetic approach to an oxabicyclobutaue derivative.2 Eowever, this hetexocyclic system has not yet been obtained, apparently a result of its facile rearraug-t to the i8americ coojugated carbonyl compound as iudicated below. In the course of related work, we have examined the peracid oxidation of several cyclopropenoues, a special class of electxoodeficient cyclopropenes,s and in the present paper we report upon the uovel txausfoxntion to acetylenes thus promoted.

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