Peracid oxidation and photooxygenation reactions of silacyclopentadienes
β Scribed by M.P. Mahajan; R. Balasubramanian; M.V. George
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 373 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Oxidation of 2 with m-chloroperbenzoic acid in the presence of SnCI4 at -78 Β°C followed by hydrolysis afforded optically active 4 in a quantitative yield. The enantiomeric excess (ee) of 4 largely depended on the reaction solvent, the chiral diol part, the Lewis acid and its amount. The best ee was
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