Stereochemistry of the Inhibition of δ-Chymotrypsin with Optically Active cis-Decaline-Type Organophosphates: 31P-NMR studies
✍ Scribed by Stefan Furegati; Walter Ganci; Georg Przibille; Peter Rüedi
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- German
- Weight
- 699 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
For a full account on the background of the project, its context, and pertinent references, see [I]. ' ) '') This finding is different from those in similar experiments with the corresponding iruns-decaline-type phosphates la and Ib, where the inhibltors never exhibited signals, and significant resonances of reaction products could be detected only after cu. 1 -2 h [l].
📜 SIMILAR VOLUMES
## Abstract The irreversible inhibition of __δ__‐chymotrypsin with the enantiomerically pure, P(3)‐axially and P(3)‐equatorially X‐substituted __cis‐__ and __trans‐__configurated 2,4‐dioxa‐3‐phospha(1,5,5‐^2^H~3~)bicyclo[4.4.0]decane 3‐oxides (X=F, 2,4‐dinitrophenoxy) was monitored by ^31^P‐NMR spe