Stereochemistry of the double bond saturation in the formation in baker's yeast of 4-(4-hydroxyphenyl)-2-butanone (raspberry ketone)
โ Scribed by Giovanni Fronza; Claudio Fuganti; Monica Mendozza; Roberta S Rallo; Gianluca Ottolina; Daniel Joulain
- Book ID
- 104207319
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 568 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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## Key Wordr cychc unsaturated a-Dlaro ketones, IMhodtum tetraacetate, Carbon-hydrogen Inserttoo, Cyclopropanahon. Selectlvlty Abstractz Dlazo carbonyl compounds, when calalyzcd by dlrhodmm tetraacetate, ~mcrt to allyhc po5ltton MS phenomenon was explmted m cychc rystems 3d, Sd, 5& and IO The rcac
Optically pure L-armentomycin t(S)-2-amino-4,4-dichlorobutanoic acid] and its D-isomer [(R)-2-amino-4,4-dichlorobutanoic acid] were prepared by using methyl (E)-and (Z)-2,4,4-trichloro-2-butenoate as key intermediate, which were reduced with baker's yeast to (R)-and (S)-2,4,4-trichlorobutanoate in 8