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Stereochemistry of the Diels?Alder reaction: steric effects of the dienophile on endo-selectivity

✍ Scribed by Mellor, John M.; Webb, Colin F.

Book ID
120321169
Publisher
Royal Society of Chemistry
Year
1974
Tongue
English
Weight
702 KB
Volume
1
Category
Article
ISSN
1472-779X

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The endo/exo stereoselectivity of the Diels-Alder cycloaddition between cyclopentadiene and 3-crotonoyl-2-oxazolidinone catalysed by Et 2 AlCl is temperature-and solvent-dependent. Eyring plots of ln(endo/exo) versus 1/T show different inversion temperatures (T inv ) depending on the reaction solven