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Electronic Effects on the Stereochemistry of the Diels—Alder Reaction 1

✍ Scribed by Kaplan, Fred; Conroy, Harold


Book ID
121303586
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
623 KB
Volume
28
Category
Article
ISSN
0022-3263

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The stereochemistry of diels-alder react
✍ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with