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Stereochemistry of the Diels-Alder reaction. V. Fluorinated trans-olefinic acids and derivatives with cyclopentadiene

✍ Scribed by McBee, Earl T.; Keogh, Michael J.; Levek, Robert P.; Wesseler, Eugene P.


Book ID
120154865
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
721 KB
Volume
38
Category
Article
ISSN
0022-3263

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## Ir(I)(coe) 2 Cl] 2 (2 mol%)-catalyzed hydrogen peroxide oxidation of hydroxamic acids in the presence of cyclopentadiene gave the corresponding cycloadducts up to 97% yield. With a catalyst loading of 0.05 mol%, a maximum TON was attained to 740.