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Stereochemistry of the carbonation of carbanions α to a chiral sulfoxide

✍ Scribed by Guy Solladie; Richard Zimmermann; Richard Bartsch


Book ID
108381843
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
220 KB
Volume
24
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


Further evidence to understand the stere
✍ Atsuyoshi Ohno; Masato Higaki; Mutsuo Okamura 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 541 KB

0 BuLi/THFIA,C=O} hHR c [ OD/020,CDaOD BuLilTHF/D20 BuLi/THF/Mei -Hs The stereochemistry of the a-sulfinyl carbanion has been studied. It has been elucidated that a 2-pyridylmethyl substituent on the sulfinyl sulfur chelates onto the counter cation in an ion pair to fix the conformation of the anio