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ChemInform Abstract: Stereochemistry of α-Sulfinyl Carbanions

✍ Scribed by A. OHNO; M. HIGAKI

Book ID
118754393
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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0 BuLi/THFIA,C=O} hHR c [ OD/020,CDaOD BuLilTHF/D20 BuLi/THF/Mei -Hs The stereochemistry of the a-sulfinyl carbanion has been studied. It has been elucidated that a 2-pyridylmethyl substituent on the sulfinyl sulfur chelates onto the counter cation in an ion pair to fix the conformation of the anio

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A PREVIOUS note from this laboratory has reported 2-octyl sulfone undergoes base-cata?yzed exchange the finding that phenyl of a-hydrogen in deuterated aqueous ethanol at a rate which is much faster than the rate of racemization.1'2 It can be conc1uded that a least 98 per cent of the benzenesulfonyl

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v