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Stereochemistry of the asymmetric reduction of (1′s)-1,3-dimethyl-4(1′-phenylethylimino)piperidine

✍ Scribed by G. V. Grishina; E. L. Gaidarova; E. R. Luk'yanenko; A. A. Borisenko

Publisher
Springer US
Year
1996
Tongue
English
Weight
218 KB
Volume
32
Category
Article
ISSN
0009-3122

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✍ Alex T. Rowland; Mark D. Winemiller; Michal Sabat 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 99 KB

Conflicting literature reports dealing with the stereochemistry of the cyclohexanone formed from the Michael reaction of dibenzalacetono with dimethyl malonate have been resolved by X-ray structure analysis. The compound is the trans isomer with a twist conformation.