๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Stereochemistry of the .alpha.-sulfinyl phenylmethyl carbanion. Reevaluation of the configuration

โœ Scribed by Nakamura, Kaoru; Higaki, Masato; Adachi, Shinichi; Oka, Shinzaburo; Ohno, Atsuyoshi

Book ID
127274006
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
460 KB
Volume
52
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Stereochemistry in the reaction of alkyl
Stereochemistry in the reaction of alkylsulfinyl phenylmethyl carbanion with electrophiles
โœ Masato Higaki; Mutsuo Goto; Atsuyoshi Ohno ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 413 KB

Stereochemistry of the reactions of methyl-, ethyl-, 2propyl-, and 1 ,I -dimethylethylsulfinyl phenylmethyl carbanions with deuterium oxide and methyl iodide in tetrahydro furan have been studied. The 2-propylsulfinyl phenylmethyl carbanion exerts abnormal behavior in the sense that the alkyl substi

Further evidence to understand the stere
Further evidence to understand the stereochemistry of the reactions of ฮฑ-sulfinyl carbanions
โœ Atsuyoshi Ohno; Masato Higaki; Mutsuo Okamura ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 541 KB

0 BuLi/THFIA,C=O} hHR c [ OD/020,CDaOD BuLilTHF/D20 BuLi/THF/Mei -Hs The stereochemistry of the a-sulfinyl carbanion has been studied. It has been elucidated that a 2-pyridylmethyl substituent on the sulfinyl sulfur chelates onto the counter cation in an ion pair to fix the conformation of the anio