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Effects of stereochemistry on the stability of alpha-nitrosamino carbanions

โœ Scribed by Robert R. Fraser; Yuk Y. Wigfield

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
245 KB
Volume
12
Category
Article
ISSN
0040-4039

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โœ Albert Padwa; M.Woods Wannamaker ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 229 KB

The effect of an electron withdrawing group adjacent to cyclopropyl carbanion has been studied. The facilitv with which carbanion interconversion occurs can be attributed to the existence of"the anomeric effect. Cyclopropyl carbanions derived from optically active precursors are capable of retaining