Stereochemistry of nucleophilic addition reactions 13 : Kinetically controlled nucleophilic addition reactions to methyl 4,6-0-benzylidene-2,3- dideoxy-2-nitro-β-D-erythro-hex-2-enopyranoside: an important role of a(1,3) strain
✍ Scribed by Tohru Sakakibara; Yoshifusa Tachmori; Rokuro Sudoh
- Book ID
- 108372739
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 718 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4020
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Reactions of the title compounds with several nucelophiles suggested that the ring oxygen atom (0-5) accelerated the reactivity of the nitro alkene moiety, but scarcely affected the stereoselectivity of the nucleophilic attack.
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