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Nucleophilic addition reactions of 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-d-erythro-hex-2-enitol and its 5a-carba derivative

✍ Scribed by Akinori Seta; Shinji Ito; Kiyohisa Tokuda; Takeshi Tamura; Yaeko Konda; Tohru Sakakibara

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 648 KB
Volume: 267
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(94)00304-x

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✦ Synopsis

Reactions of the title compounds with several nucelophiles suggested that the ring oxygen atom (0-5) accelerated the reactivity of the nitro alkene moiety, but scarcely affected the stereoselectivity of the nucleophilic attack.

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