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Stereochemistry of Ketone Olefination with Methyl Trimethylsilylacetate.

✍ Scribed by N. Ya. Grigorieva


Publisher
John Wiley and Sons
Year
2006
Weight
14 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Reaction of lithio tert-butyl trimethyls
✍ Stephen L. Hartzell; Donald F. Sullivan; Michael W. Rathke πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 164 KB

received in UK for plblicrtian 4 Maroh 1974) Addition of tert-butyl trimethylsilylacetatel to tetrahydrofuran (THF) solutions of lithium diisopropylamide at -78' produces the lithimn ester enolate, I, (eq 1) as a white precipitate. Attempts to isolate I have been unsuccessful; however, suspensions o